Will DEET insect repellent ruin your nylon climbing rope?

Takeaway: No.

Background

This has been answered many times before, yet still the web persists with seemingly authoritative sources claiming DEET is death for nylon. Unfortunately some of the most informative tests – performed by Honeywell and reported by Sterling years back – have been scrubbed from the Sterling website, now exist only as quotations. From MountainProject:

"Many climbers have in the past worried about the effects of accidentally spilling bug repellent on their climbing ropes. The following is the result of preliminary testing of deet and other bug repellent chemicals.

Samples of nylon, polyester, and spectra were submitted for chemical resistance testing for DEET (N,dimethyl-m-toluamide). The three samples were immersed separately in CUTTER and OFF brand insect repellent for a period of twenty-four hours at room temperature. OFF? contains 95% Deet (N-dimethyl-m-toluamide) while CUTTER contains only 7% Deet and probably some oil based solvents as well. The results of the testing indicate no loss of strength as measured by tensile strength retention in any of the three samples.

There was one interesting anomaly that occurred only in the case of Nylon and the "CUTTER? brand insect repellent. As mentioned before there was no loss of strength for any of the samples but here there was a 25% increase in the elongation and a decrease in modulus. This basically means that a rope made entirely or mostly out of Nylon may become “rubbery� with a significant amount of exposure to CUTTE? or other insect repellents with large amounts of oil based solvents.

However, with regard to the chemical in question, DEET, there appears to be no effect on any of the physical properties of the three samples. Hence as CUTTER? contains only 7% DEET the change in the Nylon elongation and modulus must come from the other solvents in the product. It is suggested that if a rope has significant amounts of Nylon to use insect repellents with 95-100% Deet instead of ones with some Deet and large amounts of other oil based solvents."


My Tests

So many of you are still skeptical? I did my own tests, just for familiarity. I used Sterling 5mm nylon kernmantle cord. Three samples were soaked in DEET for 4 days, then pulled out and allowed to sit for 4 days outdoors in Las Vegas, when the daytime high often exceeded 100F. Two untreated samples were kept as controls. After 4 days, the soaked cords still smelled strongly of DEET.

bens
Good old Ben's, sold in an HDPE bottle (what does that tell you about DEET and Dyneema?).
soak
Soaking.


Next I used mini-capstan clamps – made from ¾” bow shackles—to move the breaking strength to higher levels than would be obtained with knots, and used my Jeep to supply force (which was measured by a linescale 3):

bow-capstan

Results:

plot

That’s good enough for what I do. Notice all broke higher than the Sterling quoted “strength” – I suspect Sterling really tests figure-eight-to-figure-eight, or just gives a large comfort margin.

DEET does dissolve acetates and acrylics-- as in most spray paints, ABS plastics (used in some climbing helmets), eyeglass frames, some contact lenses, and the resin in Sharpie marks. In the test above, I had marked off the area where I intended to apply the DEET with Sharpie marks 2" to each side. The DEET wicked up and blurred the Sharpie marks. We are used to thinking of ABS plastic as very tough ... and it is resistant to impacts, but may get sticky if you touch it with fingers that have been used to apply DEET.  But your nylon... while it may stink... is pretty safe.